Enhanced photocurrent production from thin films of Ru(II) metallopolymer/Dawson polyoxotungstate adducts under visible irradiation.

نویسندگان

  • James J Walsh
  • Colm T Mallon
  • Alan M Bond
  • Tia E Keyes
  • Robert J Forster
چکیده

Thin films of polyoxometalates that are sensitized with a Ru(II) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, α-[P(2)W(18)O(62)](6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate α-[S(2)Mo(18)O(62)](4-).

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عنوان ژورنال:
  • Chemical communications

دوره 48 30  شماره 

صفحات  -

تاریخ انتشار 2012